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个人简介 赵佳，研究员，博士/硕士生导师，浙江省重点研发计划项目首席科学家。入选2018年浙江工业大学“青年英才支持计划”以及2022年浙江工业大学“十四五”高层次人才培育专项计划。紧扣我国氯碱产业、氟化工、医/农药、能源产业等氯资源密集应用领域的国家重大需求，长期聚焦“创制绿色催化转化与氯循环的催化剂技术”这一国际前沿科学难题的研究，注重以活性中心多尺度构筑、过程机理揭示和产物选择性调控为核心，结合原位表征技术与理论计算，提出了基于离域反应机理的多相金属离子催化剂活性中心化学微环境构建策略，在工业催化剂长周期稳定性增强技术、以及多尺度催化剂工程设计与构建方面取得了研究突破。先后主持国家重点研发计划项目子课题、浙江省科技计划项目“领雁”研发攻关计划、国家自然科学基金等国家级/省部级科研项目，以及多项重大企业横向项目。以第一作者/通讯作者在Nature Communications，ACS Catalysis，Applied Catalysis B: Environmental，Journal of Catalysis，Chemical Engineering Journal等期刊上发表SCI论文50余篇，其中ESI热点论文1篇、ESI高被引论文8篇。申请中国发明专利70余项，授权49项。 科研项目 1.  国家自然科学基金委员会，青年基金项目，21606199，配位离子液体稳定金离子价的调控力及其机制研究，20万元，已结题，主持 2.  科技部，国家重点研发计划项目子课题，2021YFA1501801，金属活性中心的多尺度构筑与可控制备，200万元，在研，主持；3.  科技部，国家重点研发计划项目子课题，2021YFA1501802，催化反应机制和再生制备的技术基础研究，103万元，在研，主持4.  浙江省科技厅，“尖兵”“领雁”研发攻关计划项目，2023C01211，乙烯产业关键单体用高性能催化剂的研发与应用，250万元，在研，主持5.  浙江省科技计划项目-公益技术，基于电中性配位机理构建升华型催化剂活性组分的稳定机制研究，10万元，已结题，主持6.  国家自然科学基金委员会，联合基金重点项目，U20A20119，金属@碳封装催化剂体系的活性位形成及活性增强机制研究，280万元，在研，参与7.  国家自然科学基金委员会，面上项目，21476207，含氮碳材料双碱性位于催化脱氯化氢合成偏二氯乙烯性能研究，100万元，已结题，参与  8.  国家自然科学基金委员会，青年基金项目，21506138，介孔碳材料中氮碳原子比与堆积形态的调控及催化性能研究，25万元，已结题，参与 科研成果 学术论文[1] Luyao Guo, Kaixuan Zhuge, Siyang Yan, Shiyi Wang, Jia Zhao*, Saisai Wang, Panzhe Qiao, Jiaxu Liu*, Xiaoling Mou, Hejun Zhu*, Ziang Zhao, Li Yan, Ronghe Lin*, Yunjie Ding*, Defect-driven nanostructuring of low-nuclearity Pt-Mo ensembles for continuous gas-phase formic acid dehydrogenation, Nature Communications, 2023, 14:7518-7529[2] Yuxue Yue, Saisai Wang, Qi Zhou, Bolin Wang, Chunxiao Jin, Renqin Chang, Liqi Wan, Zhiyan Pan, Yihan Zhu, Jia Zhao*, Xiaonian Li*, Tailoring Asymmetric Cu-O-P Coupling Site by Carbothermal Shock Method for Efficient Vinyl Chloride Synthesis over Carbon Supported Cu Catalysts, ACS Catalysis, 2023, 13: 9777-9791.[3] Saisai Wang, Liqi Wan, Chunxiao Jin, Tao Wang, Kaixuan Zhuge, Yuxue Yue, Haiting Cai, Bolin Wang, Renqin Chang, Jia Zhao*, Xiaonian Li, Mechanistic insight into acetylene hydrochlorination with Ru-ligands via dual activation promoted by metal-ligands cooperative catalysis, Applied Catalysis A: General, 2023, 665: 119382-119391.[4] Feng Feng, Chunxiao Jin, Saisai Wang, Yuxue Yue, Da Xu, Kaixuan Zhuge, Pan Gao, Jia Zhao, Renqin Chang, Lingling Guo, Huaqing Dong*, Self-oxidation of Au-[Bmim][Cl3] catalyst with enhanced activity and stability for acetylene hydrochlorination, Applied Catalysis A: General, 2023, 661: 119238-119248.[5] Huijun Song, Xiaoqiu Xu, Jingjing Chen, Yinling Zhang, Jia Zhao, Chongzhi Zhu, Hong Zhang, Yong Peng, Qiaoli Chen, Guan Sheng, Tulai Sun, Yu Han, Xiaonian Li, Yihan Zhu*, Evoking Cooperative Geometric and Electronic Interactions at Nanometer Coherent Interfaces toward Enhanced Electrocatalysis, Advanced Functional Materials: 2023, 33: 2301490-2301503.[6] Zilong Zhang, Haifeng Zhang*, Bolin Wang*, Yuxue Yue, Jia Zhao*, Migration: A Neglected Potential Contribution of HCl-Oxidized Au(0). Molecules, 2023, 28: 1600. https://doi.org/10.3390/molecules28041600.[7] Rongrong Li, Yuxue Yue, Yongkun Li, Xianlang Chen, Renqin Chang, Jiaxin Zhang, Bo Zhao, Xia Ying, Zijian Wang, Jia Zhao*, Xiaonian Li, Controlling the speciation and selectivity of Si3N4 supported palladium nanostructures for catalysed acetylene selective hydrogenation, Inorganic Chemistry Frontiers: 2022, 9, 5969-5982.[8] Rongrong Li, Yuxue Yue, Xianlang Chen, Renqin Chang, Jiaxin Zhang, Bo Zhao, Jieyu Zhang, Di Cai, Yihan Zhu, Deman Han, Jia Zhao*, Xiaonian Li, Graphdiyne anchoring to construct highly dense palladium trimer active sites for the selective hydrogenation of acetylene, Nano Research, 2022, 16: 6167-6178.[9] Zhongting Hu, Wenhao Xing, Siyan Gong, Tulai Sun, Cheng Wang, Mian Hu, Jia Zhao*, Zhiyan Pan, Wei Chen*, Zhong Chen, Xiaonian Li. Flower-like ZnIn2S4 microspheres with highly efficient catalytic activity for visible-light-driven sulfamethoxazole photodegradation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 643: 128779-128788.[10] Bolin Wang, Haifeng Zhang*, Yuxue Yue, Changlin Li, Jia Zhao*, Catalytic Behavior of Au Confined in Ionic Liquid Film: A Kinetics Study for the Hydrochlorination of Acetylene, Catalysts, 2022, 12: 1012-1021.[11] Bolin Wang, Chunxiao Jin, Shujuan Shao, Yuxue Yue, Yuteng Zhang, Saisai Wang, Renqin Chang, Haifeng Zhang*, Jia Zhao*, Xiaonian Li*. Electron-deficient Cu site catalyzed acetylene hydrochlorination. Green Energy & Environment, 2022. 8: 1128-1140.[12] Ting Wang, Zhao Jiang, Qi Tang, Bolin Wang, Saisai Wang, Mingde Yu, Renqin Chang, Yuxue Yue, Jia Zhao*, Xiaonian Li*. Interactions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene. Communications Chemistry, 2022. https://doi.org/10.1038/s42004-021-00619-7.[13] Mengru Wang, Yuxue Yue, Yi Wang, Xiaoling Mou, Renqin Chang, Zupeng Chen, Ronghe Lin*, Jia Zhao*, Yunjie Ding*. Selective hydrogenation of 1,3-butadiene on iridium nanostructures: Structure sensitivity, host effect, and deactivation mechanism. Journal of Energy Chemistry, 2022, 69: 541-554.[14] Qi Tang, Yuxue Yue, Zhao Jiang, Feibiao Li, Ting Wang, Chunxiao Jin, Huaqing Dong*, Renqin Chang, Bolin Wang, Haiting Cai, Jia Zhao*, Xiaonian Li. Non-metallic carbon-based catalysts for acetylene hydrochlorination: The effect of graphitization degree of carbonaceous material. Catalysis Communications, 2022, 167: 106458-106463.[15] Zhongting Hu, Yin Ding, Yuchao Shao, Luxiang Cai, Ziyan Jin, Zifeng Liu, Jia Zhao, Feili Li*, Zhiyan Pan, Xiaonian Li, Jun Zhao*. Banana peel biochar with nanoflake-assembled structure for cross contamination treatment in water: Interaction behaviors between lead and tetracycline. Chemical Engineering Journal, 2021, 420: 129807.[16] Bolin Wang, Zhao Jiang, Ting Wang, Qi Tang, Mingde Yu, Tao Feng, Min Tian, Renqin Chang, Yuxue Yue, Zhiyan Pan, Jia Zhao*, Xiaonian Li*. Controllable Synthesis of Vacancy-Defect Cu Site and Its Catalysis for the Manufacture of Vinyl Chloride Monomer. ACS Catalysis, 2021, 11: 11016-11028. [17] Bolin Wang,Yuxue Yue, Xiangxue Pang, Mingde Yu, Ting Wang, Renqin Chang, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Nature of HCl oxidation Au anomalies and activation of non-carbon-material-supported Au catalyst. Journal of Catalysis, 2021, 404: 198-203.[18] Jia Zhao*, Saisai Wang, Bolin Wang, Yuxue Yue, Jinyue Lu, Jinyue Lu, Zheng Fang, Xiangxue Pang, Feng Feng, Lingling Guo, Zhiyan Pan, Xiaonian Li. Acetylene hydrochlorination over suppopported ionic liquid phase(SILP) gold-based catalyst: stabilization of cationic Au species via chemical activation of hydrogen chloride and corresponding mechanisms. Chinese Journal of Catalysis, 2021, 42(2): 334-346.[19] Bolin Wang, Yuxue Yue, Xiangxue Pang, Wenrui Zhu, Zhi Chen, Shujuan Shao, Ting Wang, Zhiyan Pan, Xiaonian Li, Jia Zhao*. Synergistic effect of two action sites on a nitrogen-doped carbon catalyst towards acetylene hydrochlorination. Physical Chemistry Chemical Physics, 2020, 22, 20995-20999.[20] Bolin Wang, Yuxue Yue, Saisai Wang, Shujuan Shao, Zhi Chen, Xianhua Fang, Xiangxue Pang, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Stabilizing supported gold catalysts in acetylene hydrochlorination by constructing an acetylene-deficient reaction phase. Green Energy & Environment, 2020.(Doi:10.1016/j.gee.2020.06.012)[21] Bolin Wang, Yuxue Yue, Chunxiao Jin, Jinyue Lu, Saisai Wang, Lu Yu, Lingling Guo, Rongrong Li, Zhong-Ting Hu, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Hydrochlorination of acetylene on single-atom Pd/N-doped carbon catalysts: Importance of pyridinic-N synergism. Applied Catalysis B: Environmental, 2020, 272, 118944-118954.[22] Rongrong Li, Yuxue Yue, Zhi Chen, Xianlang Chen, Saisai Wang, Zhao Jiang, Bolin Wang, Qianqian Xu, Deman Han, Jia Zhao*. Selective hydrogenation of acetylene over Pd-Sn catalyst: Identification of Pd2Sn intermetallic alloy and crystal plane-dependent performance. Applied Catalysis B: Environmental, 2020, 279, 119348-119358.[23] Bolin Wang, Yuxue Yue, Saisai Wang, Zhi Chen, Lu Yu, Shujuan Shao, Guojun Lan, Zhiyan Pan, Jia Zhao*, Xiaonian Li. Constructing and controlling ruthenium active phases for acetylene hydrochlorination. Chemical Communications, 2020, 56, 10722-10725.[24] Yaqing Cen, Yuxue Yue, Saisai Wang, Jinyue Lu, Bolin Wang, Chunxiao Jin, Lingling Guo, Zhongting Hu, Jia Zhao*. Adsorption behaivor and electron structure engineering of Pd-based catalysts for acetylene hydrochlorination. catalysts, 2020, 10(1): 24-37.[25] Yuxue Yue, Bolin Wang, Saisai Wang, Chunxiao Jin, Jinyue Lu, Zheng Fang, Shujuan Shao, Zhiyan Pan, Jun Ni, Jia Zhao*, Xiaonian Li. Boron-doped carbon nanodots dispersed on graphitic carbon as high-performance catalysts for acetylene hydrochlorination. Chemical Communications, 2020, 56, 5174-5177.[26] Yi Yu, Yuxue Yue, Bolin Wang, Haihua He, Zhong-Ting Hu, Jia Zhao*, Xiaonian Li. Synergy between ionic liquids and CuCl2 in gas–liquid phase reactions of acetylene hydrochlorination. Catalysts, 2019, 9(6): 504-525.[27] Haihua He, Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Qingtao Wang, Lu Yu, Zhong-Ting Hu, Xiaonian Li. Highly active AuCu-based catalysts for acetylene hydrochlorination prepared using organic aqua regia. Materials, 2019, 12(8): 1310-1323.[28] Yuxue Yue, Bolin Wang, Gangfeng Sheng, Huixia Lai, Saisai Wang, Zhi Chen, Zhong-Ting Hu, Jia Zhao*, Xiaonian Li. An ultra-high H2S-resistant gold-based imidazolium ionic liquid catalyst for acetylene hydrochlorination. New Journal of Chemistry, 2019, 43, 12767-12775.[29] Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Saisai Wang, Lu Yu, Qunfeng Zhang, Feng Feng, Zhong-Ting Hu, Xiaonian Li. Nitrogen- and phosphorus-codoped carbon-based catalyst for acetylene hydrochlorination. Journal of Catalysis, 2019, 373: 240-249.[30] Huixia Lai, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Saisai Wang, Feng Feng, Qunfeng Zhang, Jia Zhao*, Xiaonian Li. An Alternative Carbon Carrier in Green Preparation of Efficient Gold/Carbon Catalyst for Acetylene Hydrochlorination. ChemCatChem, 2019, 11(14): 3318-3326.[31] Haihua He, Jia Zhao*, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Qingtao Wang, Lu Yu, Zhong-Ting Hu, Xiaonian Li. Design strategies for the development of a Pd-based acetylene hydrochlorination catalyst: improvement of catalyst stability by nitrogen-containing ligands. RSC Advances, 2019, 9, 21557-21563.[32] Jia Zhao*, Yuxue Yue, Gangfeng Sheng, Bolin Wang, Huixia Lai, Shuxia Di, Yuanyuan Zhai, Lingling Guo, Xiaonian Li*. Supported ionic liquid-palladium catalyst for the highly effective hydrochlorination of acetylene, Chemical Engineering Journal, 2019, 360, 38-46.[33] Bolin Wang, Jia Zhao*, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Jiayao Rui, Haihua He, Zhongting Hu, Feng Feng, Qunfeng Zhang, Lingling Guo, Xiaonian Li*. Carbon with Surface-Enriched Nitrogen and Sulfur Supported Au Catalysts for Acetylene Hydrochlorination, ChemCatChem, 2019, 11, 1002-1009.[34] Bolin Wang, Huixia Lai, Yuxue Yue, Gangfeng Sheng, Yaqin Deng, Haihua He, Lingling Guo, Jia Zhao*, Xiaonian Li*. Zeolite Supported Ionic Liquid Catalysts for the Hydrochlorination of Acetylene, Catalysts, 2018, 8, 351-363.[35] Shuxia Di, Yiqi Xu, Qunfeng Zhang, Xiaolong Xu, Yuanyuan Zhai, Bolin Wang, Haihua He, Qingtao Wang, Hao Xu, Yishu Jiang, Jia Zhao, Xiaonian Li. Insight into the dispersion behavior of 1-butyl-3-methylimiazolium chloride confined in nanoscale pores of carbon materials. RSC Advances, 2018, 8(43): 24094-24100.[36] Jia Zhao*, Bolin Wang, Yuxue Yue, Shuxia Di, Yuanyuan Zhai, Haihua He, Gangfeng Sheng, Huixia Lai, Yihan Zhu, Lingling Guo, Xiaonian Li*. Towards a greener approach for the preparation of highly active gold/carbon catalyst for the hydrochlorination of ethyne, Journal of Catalysis, 2018, 365, 153-162.[37] Yuanyuan Zhai, Jia Zhao*, Xiaoxia Di, Shuxia Di, Bolin Wang, Yuxue Yue, Gangfeng Sheng, Huixia Lai, Lingling Guo, Hong Wang and Xiaonian Li*. Carbon-supported perovskite-like CsCuCl3 nanoparticles: a highly active and cost-effective heterogeneous catalyst for the hydrochlorination of acetylene to vinyl chloride. Catal. Sci. Technol., 2018, 8, 2901-2908.[38] Jia Zhao*, Bolin Wang, Xiaolong Xu, Yi Yu, Shuxia Di, Hao Xu, Yuanyuan Zhai, Haihua He, Lingling Guo, Zhiyan Pan, Xiaonian Li*. Alternative solvent to aqua regia to activate Au/AC catalysts for the hydrochlorination of acetylene, Journal of Catalysis, 2017, 350: 149-158.[39] Jia Zhao*, Yi Yu, Xiaolong Xu, Shuxia Di, Bolin Wang, Hao Xu, Jun Ni, LingLing Guo, Zhiyan Pan, Xiaonian Li*. Stabilizing Au(III) in supported-ionic-liquid-phase (SILP) catalyst using CuCl2 via a redox mechanism. Applied Catalysis B: Environmental, 2017, 206: 175-183.[40] Xiaolong Xu, Haihua He, Jia Zhao, Bailin Wang, Shanchuan Gu, Xiaonian Li. The ligand coordination approach for improving the stability of low-mercury catalyst in the hydrochlorination of acetylene. Chinese Journal of Chemical Engineering, 2017, 25(9): 1217-1221.[41] Rongrong Li, Jia Zhao, Deman Han, Xiaonian Li. One-step synthesis of B-doped mesoporous carbon as supports of Pd nanoparticles for liquid phase catalytic hydrodechlorination. Catalysis Communications, 2017, 97, 116-119.[42] Xiaolong Xu, Jia Zhao, Chunshan Lu, Xiaoxia Di, Shanchuan Gu, Xiaonian Li. Improvement of the stability of Hg/AC catalysts by CsCl for the high-temperature hydrochlorination of acetylene. Chinese Chemical Letters, 2016, 27(6): 822-826.[43] Jia Zhao, Shanchuan Gu, Xiaolong Xu, Tongtong Zhang, Yi Yu, Xiaoxia Di, Jun Ni, Zhiyan Pan and Xiaonian Li*. Supported ionic-liquid-phase-stabilized Au(III) catalyst for acetylene hydrochlorination. Catalysis Science & Technology, 2016, 6, 3263-3270.[44] Tongtong Zhang, Jia Zhao, Jiangtao Xu, Jinhui Xu, Xiaoxia Di, Xiaonian Li*. Oxygen and Nitrogen-doped Metal-free Carbon Catalysts for Hydrochlorination of Acetylene. Chinese Journal of Chemical Engineering, 2016, 34, 484-490.[45] Xiao-Xia Di, Jia Zhao, Yi Yu, Xiao-Long Xu, Shan-Chuan Gu, HaiHua He, Tong-Tong Zhang, Xiao-Nian Li*. One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl3 as efficient catalysts for acetylene hydrochlorination. Chinese Chemical Letters, 2016, 27, 1567-1571.[46] Jun Ni, Jia Zhao, Luwei Chen, Jianyi Lin, Sibudjing Kawi. Lewis Acid Sites Stabilized Nickel Catalysts for Dry (CO2) Reforming of Methane. ChemCatChem, 2016, 8(24):3732-3739.[47] Jia Zhao, Tongtong Zhang, Xiaoxia Di, Jiangtao Xu, Shanchuan Gu, Qunfeng Zhang*, Jun Ni and Xiaonian Li*. Activated carbon supported ternary gold-cesium(I)-indium(III) catalyst for the hydrochlorination of acetylene. Catalysis Science & Technology, 2015, 5, 4973-4984.[48] Jia Zhao, Shanchuan Gu, Xiaolong Xu, Tongtong Zhang, Xiaoxia Di, Zhiyan Pan and Xiaonian Li*. Promotional effect of copper(II) on an activated carbon supported low content bimetallic gold-cesium(I) catalyst in acetylene hydrochlorination. RSC Advances, 2015, 5, 101427-101436.[49] Jia Zhao, Jiangtao Xu, Jinhui Xu, Tongtong Zhang, Xiaoxia Di, Jun Ni, Xiaonian Li*. Enhancement of Au/AC acetylene hydrochlorination catalyst activity and stability via nitrogen-modified activated carbon support. Chemical Engineering Journal, 2015, 262, 1152-1160.[50] Jia Zhao, Tongtong Zhang, Xiaoxia Di, Jiangtao Xu, Jinhui Xu, Feng Feng, Jun NI and Xiaonian Li*. Nitrogen-modified activated carbon supported bimetallic gold-cesium(I) as highly active and stable catalyst for the hydrochlorination of acetylene. RSC Advances, 2015, 5(9): 6925-6931.[51] Jiangtao Xu, Jia Zhao, Tongtong Zhang, Xiaoxia Di, Shanchuan Gu, Jun Ni and Xiaonian Li*. Ultra-low Ru-promoted CuCl2 as highly active catalyst for the hydrochlorination of acetylene. RSC Advances, 2015, 5: 38159-38163.[52] Jia Zhao, Jiangtao Xu, Jinhui Xu, Jun Ni, Tongtong Zhang, Xiaoliang Xu and Xiaonian Li*. Activated-Carbon-Supported Gold-Cesium(I) as Highly Effective Catalysts for Hydrochlorination of Acetylene to Vinyl Chloride. ChemPlusChem, 2014, 80(1): 196-201.[53] Jinhui Xu, Jia Zhao, Jiangtao Xu, Tongtong Zhang, Xiaonian Li*, Xiaoxia Di, Jun Ni, Jianguo Wang* and Jie Cen. Influence of Surface Chemistry of Activated Carbon on the Activity of Gold/Activated Carbon Catalyst in Acetylene Hydrochlorination. Industrial & Engineering Chemistry Research, 2014, 53(37): 14272-14281.[54] Jia Zhao, Xiaoliang Xu, Xiaonian Li* and Jianguo Wang*. Promotion of Sn on the Pd/AC catalyst for the selective hydrogenation of cinnamaldehyde. Catalysis Communications, 2014, 43: 102-106.[55] Jia Zhao, Lei Ma, Xiaoliang Xu, Feng Feng and Xiaonian Li*. Synthesis of carbon-supported Pd/SnO2 catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene. Chinese Chemical Letters, 2014, 25: 1137-1140.[56] Jia Zhao, Jun Ni, Jinhui Xu, Jiangtao Xu, Jie Cen and Xiaonian Li*. Ir promotion of TiO2 supported Au catalysts for selective hydrogenation of cinnamaldehyde. 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