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导航 个人简介 学习经历 工作经历 研究方向 主要论文 主要著作 承担课题,个人信息 姓名： 袁尚富 部门： 化学与材料学院 直属机构： 超分子配位化学研究所 性别： 男 职称： 教授 学位： 博士 毕业院校： 厦门大学 电子邮箱： sfyuan@jnu.edu.cn 办公地址： 化学与材料学院205c 通讯地址： 广东省广州市天河区暨南大学化学与材料学院205c 邮编： 510632 联系方式 1）邮箱：sfyuan@jnu.edu.cn 个人简介 袁尚富，暨南大学特聘教授。2012-2018年，硕博连读于厦门大学；2018-2020年，于清华大学化学系开展博士后工作，师从王泉明教授。2021年11月，就职于暨南大学化学与材料学院，加入超分子配位化学研究所吴涛教授和李丹教授团队。针对金属纳米团簇催化的两大难题（催化位点活性低和催化剂稳定性差），以“配体工程”为切入点，开创胺配体修饰纳米团簇新体系，实现团簇的结构和稳定性调控；设计“表面几何错配”策略，构建团簇表面不饱和位点，极大提高了催化活性。近五年以第一或通讯作者在 Nat. Commun.（1篇）、J. Am. Chem. Soc.（3篇）、Angew. Chem. Int.Ed.（4篇）、Nanoscale (2篇)等高水平学术期刊发表多篇代表性论作，其中一篇为封面文章，两篇为热点论文，两篇入选高被引论文（论文引用次数超过1600次，H-index为21）。主持/参与多项国家级科研项目，包括青年基金（主持）、重大研究计划（第三位）和联合基金重点支持项目（第二单位主持）；获批中国发明专利1项。相关成果被Wiley新闻部等平台报道和同行引用。受邀担任《稀有金属》青年编委，多次参加学术会议，并获ACS青年论坛奖。 学习经历 2012/09-2018/06，博士，物理化学，厦门大学（硕博连读）2008/09-2012/06，学士，应用化学，华东交通大学。 工作经历 2018/07-2020/11，博士后，无机化学，化学系，清华大学。2021/11-至今，教授，超分子配位化学研究所，化学与材料学院，暨南大学。 研究方向 1）金属团簇化学与配位化学；2）原子精确团簇基纳米材料的结构与催化；3）层状配位合物的组装与功能化。欢迎对上述领域感兴趣的博士后、研究生及本科生加入实验室。 主要论文 参加工作后：1) Hu, F.; Luyang, H. W.; He, R. L.; Guan, Z. J.; Yuan, S. F.*; Wang, Q. M.*, Face-Centered Cubic Silver Nanoclusters Consolidated with Tetradentate Formamidinate Ligands. J. Am. Chem. Soc. 2022, 144, 19365-19371. (Link)2) Sun, P.; Xie, M.; Zhang, L.-M.; Liu, J.-X.; Wu, J.; Li, D.-S.; Yuan, S.-F.*; Wu, T.*; Li, D.*, Ultrastable Anti-Acid 'Shield' in Layered Silver Coordination Polymers. Angew. Chem. Int. Ed. 2022, e202209971. (Link)3) Yuan, S.-F.; Guan, Z.-J.; Wang, Q.-M.*, Identification of the Active Species in Bimetallic Cluster Catalyzed Hydrogenation. J. Am. Chem. Soc. 2022, 144, 11405. (Link)4) Cheng, X.; Zhong, R. R.; Yuan, S.-F.*; Guan, Z.-J.*; Liu, K.-G.*, Compact accumulation of superatomic silver nanoclusters with an octahedral Ag6 core ligated by trithiane. Nanoscale 2022,14, 10321-10326. (Link)5) Sun, P.; Tang, X.; Yang, W.; Wang, X.; Zhou, R.*; Chen, N.; Yuan, S. F.*, N-Heterocyclic Thione-Protected Ag4 Tetrahedra and Ag8 Cubes Cocrystallized in a Single Crystal. Inorg. Chem. 2022, 61, 9251-9256. (Link)6) Yuan, S. F.; Liu, W. D.; Liu, C. Y.; Guan, Z. J.; Wang, Q. M.*, Nitrogen Donor Protection for Atomically Precise Metal Nanoclusters. Chem. Eur. J. 2022, 28, e202104445. (Link)7) Zhang, L.-M.; Kong, Y.; Zhou, R.*; Yuan, S.-F.*; Wu, T., X-ray photochromism of chalcogenide frameworks linked with metal-amine chelates. Chem. Commun. 2022, 10.1039/D2CC05407H. (Link)8) Liu, C.-Y.; Yuan, S.-F.; Wang, S.; Guan, Z.-J.; Jiang, D.-e.; Wang, Q.-M.* Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters. Nat. Commun. 2022,13, 2082. (Link)9) Guan, Z.-J.; He, R.-L.; Yuan, S.-F.; Li, J.-J.; Hu, F.; Liu, C.-Y.; Wang, Q.-M.* Ligand Engineering toward the Trade-Off between Stability and Activity in Cluster Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202116965. (Link)参加工作前：1) Yuan, S.-F.; Xu, C.-Q.*; Liu W. D.; Zhang J.-X. Li, J.; Wang, Q.-M.* Rod-shaped silver supercluster unveiling strong electron coupling between substituent icosahedral units. J. Am. Chem. Soc. 2021, 143, 12261.(Link)2) Yuan, S.-F.; He R.-L.; Han X.-S.; Wang J.-Q.; Guan, Z.-J.; Wang, Q.-M.* Robust gold nanocluster protected with amidinates for electrocatalytic CO2 reduction. Angew. Chem., Int. Ed. 2021, 60, 14345. (Link)3) Yuan, S.-F.; Luyang H.-W.; Lei, Z.; Wan, X.-K.; Li, J.-J.; Wang, Q.-M.* A stable well-defined copper hydride cluster consolidated with hemilabile phosphines. Chem.Commun. 2021, 57, 4315. (Link)4) Yuan, S.-F.; Guan, Z.-J.; Lei, Z.; Wang, Q.-M.* Atomically precise preorganization of open metal sites on gold nanocluster with high catalytic performance. Angew. Chem. Int. Ed. 2021, 60, 5225. (Link)5)Yuan, S.-F.; Li J.-J.; Guan, Z.-J.; Lei, Z.; Wang, Q.-M.* Ultrastable Hydrido Gold Nanoclusters with the Protection of Phosphines. Chem.Commun. 2020, 56, 7037. (Link)6) Yuan, S.-F.; Guan, Z.-J.; Liu, W.-D.; Wang, Q.-M.* Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties.Nat. Commun. 2019, 10, 4032. (Link)7) Yuan, S.-F.#; Xu, C. Q.#; Li, J.*; Wang, Q.-M.* A Ligand-Protected Golden Fullerene: The Dipyridylamido Au328+ Nanocluster. Angew. Chem., Int. Ed. 2019, 58, 5906. (Link)8) Yuan, S.-F.; Li, P.; Tang, Q.; Wan, X. -K.; Nan, Z.-A.; Jiang, D.-E.; Wang, Q.-M.* Alkynyl-protected silver nanoclusters featuring an anticuboctahedral kernel. Nanoscale 2017, 9, 11405. (Link)9) Lei, Z.; Wan, X.-K.; Yuan, S.-F.; Guan, Z.-J.; Wang, Q.-M.* Alkynyl Approach toward the Protection of Metal Nanoclusters. Acc. Chem. Res. 2018, 51, 2465. (Link)10) Liu, W.-D.; Wang, J.-Q.; Yuan, S.-F.; Chen, X.; Wang, Q.-M., Chiral Superatomic Nanoclusters Ag47 Induced by the Ligation of Amino Acids. Angew. Chem. Int. Ed. 2021, 60, 11430-11435. (Link)11) Li, J.-J.; Guan, Z.-J.; Yuan, S.-F.; Hu, F.; Wang, Q.-M., Enriching Structural Diversity of Alkynyl-Protected Gold Nanoclusters with Chlorides. Angew. Chem. Int. Ed. 2021, 60, 6699-6703. (Link)12) Hu, F.; Guan, Z.-J.; Yang, G.; Wang, J.-Q.; Li, J.-J.; Yuan, S.-F.; Liang, G.-J.; Wang, Q.-M., Molecular Gold Nanocluster Au156 Showing Metallic Electron Dynamics. J. Am. Chem. Soc. 2021, 143, 17059-17067. (Link)13) Wang, J.-Q.; Shi, S.; He, R.-L.; Yuan, S.-F.; Yang, G.-Y.; Liang, G.-J.; Wang, Q.-M., Total Structure Determination of the Largest Alkynyl-Protected fcc Gold Nanocluster Au-110 and the Study on Its Ultrafast Excited-State Dynamics. J. Am. Chem. Soc. 2020, 142, 18086-18092. (Link)14) Hu, F.; Li, J.-J.; Guan, Z.-J.; Yuan, S.-F.; Wang, Q.-M., Formation of an Alkynyl-Protected Ag-112 Silver Nanocluster as Promoted by Chloride Released In Situ from CH2Cl2. Angew. Chem. Int. Ed. 2020, 59, 5312-5315. (Link)15) Han, X.-S.; Luan, X.; Su, H.-F.; Li, J.-J.; Yuan, S.-F.; Lei, Z.; Pei, Y.; Wang, Q.-M., Structure Determination of Alkynyl-Protected Gold Nanocluster Au22(tBuC≡C)18 and Its Thermochromic Luminescence. Angew. Chem. Int. Ed. 2020, 59, 2309-2312. (Link)16) Yang, Y.; Jia, T.; Han, Y.-Z.; Nan, Z.-A.; Yuan, S.-F.; Yang, F.-L.; Sun, D., An All-Alkynyl Protected 74-Nuclei Silver(I)-Copper(I)-Oxo Nanocluster: Oxo-Induced Hierarchical Bimetal Aggregation and Anisotropic Surface Ligand Orientation. Angew. Chem. Int. Ed. 2019, 58, 12280-12285. (Link)17) Guan, Z.-J.; Hu, F.; Yuan, S.-F.; Nan, Z.-A.; Lin, Y.-M.; Wang, Q.-M., The stability enhancement factor beyond eight-electron shell closure in thiacalix[4]arene-protected silver clusters. Chem. Sci. 2019, 10, 3360-3365. (Link)18) Wang, T.; Zhang, W. H.; Yuan, S. F.; Guan, Z. J.; Wang, Q. M., An alkynyl-protected Au40 nanocluster featuring PhC≡C–Au–P^P motifs. Chem. Commun.2018, 54, 10367-10370. (Link)19) Nan, Z.-A.; Wang, Y.; Chen, Z.-X.; Yuan, S.-F.; Tian, Z.-Q.; Wang, Q.-M., Catalyzed assembly of hollow silver-sulfide cluster through self-releasable anion template. Commun. Chem. 2018,1, 99. (Link)20) Guan, Z.-J.; Zeng, J.-L.; Yuan, S.-F.; Hu, F.; Lin, Y.-M.; Wang, Q.-M., Au57Ag53(C CPh)40Br12: A Large Nanocluster with C-1 Symmetry. Angew. Chem. Int. Ed. 2018, 57, 5703-5707. (Link)21) Lei, Z.; Wan, X.-K.; Yuan, S.-F.; Wang, J.-Q.; Wang, Q.-M., Alkynyl-protected gold and gold-silver nanoclusters. Dalton Trans. 2017, 46, 3427-3434. (Link)22) Lei, Z.; Guan, Z.-J.; Pei, X.-L.; Yuan, S.-F.; Wan, X.-K.; Zhang, J.-Y.; Wang, Q.-M., An Atomically Precise Au10Ag2 Nanocluster with Red-Near-IR Dual Emission. Chem.- Eur. J. 2016, 22, 11156-11160. (Link)23) Yin, J.; Cao, J.; He, X.; Yuan, S.; Sun, S.; Li, J.; Zheng, N.; Lin, L., Improved stability of perovskite solar cells in ambient air by controlling the mesoporous layer. J. Mater. Chem. A 2015, 3, 16860-16866. (Link)24) Wan, X.-K.; Xu, W. W.; Yuan, S.-F.; Gao, Y.; Zeng, X.-C.; Wang, Q.-M., A Near-Infrared-Emissive Alkynyl-Protected Au-24 Nanocluster. Angew. Chem. Int. Ed. 2015,54, 9683-9686. (Link)25) Wan, X.-K.; Yuan, S.-F.; Tang, Q.; Jiang, D.-E.; Wang, Q.-M.* Alkynyl-protected Au23 nanocluster: a 12-electron system. Angew. Chem., Int. Ed. 2015, 54, 5977. (Link)26) Wan, X.-K.; Tang, Q.; Yuan, S.-F.; Jiang, D.-e.; Wang, Q.-M., Au-19 Nanocluster Featuring a V-Shaped Alkynyl-Gold Motif. J. Am. Chem. Soc. 2015,137, 652-655. (Link)27) Cao, J.; Yin, J.; Yuan, S.; Zhao, Y.; Li, J.; Zheng, N., Thiols as interfacial modifiers to enhance the performance and stability of perovskite solar cells. Nanoscale 2015,7, 9443-9447. (Link)28) Wan, X.-K.; Yuan, S.-F.; Lin, Z.-W.; Wang, Q.-M., A Chiral Gold Nanocluster Au-20 Protected by Tetradentate Phosphine Ligands. Angew. Chem. Int. Ed. 2014, 53, 2923-2926. (Link) 承担课题 国家自然科学基金-青年基金                     （主持）国家自然科学基金-重大研发计划              （项目骨干）国家自然科学基金-联合基金重点支持项目 （第二单位主持）暨南大学第四层次人才引进启动经费         （主持）暨南大学学科建设优秀青年骨干项目         （主持）暨南大学中央高校基本科研业务项目         （主持） 发明专利 1）王泉明，袁尚富；多铜团簇及其制备方法，中国发明专利。NO. ZL201811018728.1 (CN 110872311B) 讲授课程 1） 基础化学；2）超分子配位化学；3）无机材料化学前沿与展望；4）无机化学实验；5）基础化学实验。 社会职务 担任Rare Metals青年编委